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mechanism of arsenic capture by a calcium-based sorbent during the combustion of arsenic-contaminated biomass

Mei Lei, Ziping Dong, Ying Jiang, Philip Longhurst, Xiaoming Wan, Guangdong Zhou

《环境科学与工程前沿(英文)》 2019年 第13卷 第2期 doi: 10.1007/s11783-019-1110-y

摘要:

Pilot-scale combustion is required to treat arsenic-enriched biomass in China.

CaO addition to arsenic-enriched biomass reduces arsenic emission.

CaO captures arsenic via chemical adsorption to form Ca3(AsO4)2.

关键词: Arsenic contamination     Phytoremediation     Emission control     Calcium-based sorbent     Biomass disposal     Pilot-scale combustion    

Nitrogen-retaining property of compost in an aerobic thermophilic composting reactor for the sanitary disposal

Fan BAI, Xiaochang WANG,

《环境科学与工程前沿(英文)》 2010年 第4卷 第2期   页码 228-234 doi: 10.1007/s11783-010-0022-7

摘要: Aerobic composting is a method for the sanitary disposal of human feces as is used in bio-toilet systems. As the products of composting can be utilized as a fertilizer, it would be beneficial if the composting conditions could be more precisely controlled for the retention of fecal nitrogen as long as possible in the compost. In this study, batch experiments were conducted using a closed aerobic thermophilic composting reactor with sawdust as the bulk matrix to simulate the condition of a bio-toilet for the sanitary disposal of human feces. Attention was paid to the characteristics of nitrogen transformation. Under the controlled conditions of temperature at 60°C, moisture content at 60%, and a continuous air supply, more than 70% fecal organic removal was obtained, while merely 17% fecal nitrogen loss was observed over a two-week composting period. The nitrogen loss was found to occur mainly in the first 24 h with the rapid depletion of inorganic nitrogen but with an almost unchanged organic nitrogen content. The fecal NH–N which was the main component of the inorganic nitrogen (>90%) decreased rapidly in the first day, decreased at a slower rate over the following days, and finally disappeared entirely. The depletion of NH–N was accompanied by the accumulation of NH gas in the ammonia absorber connected to the reactor. A mass balance between the exhausted NH gas and the fecal NH–N content in the first 24 hours indicated that the conversion of ammonium into gaseous ammonia was the main reason for nitrogen loss. Thermophilic composting could be considered as a way to keep a high organic nitrogen content in the compost for better utilization as a fertilizer.

关键词: nitrogen retention     composting reactor     human feces     aerobic     thermophilic     fertilizer    

Exploring the development of municipal solid waste disposal facilities in Chinese cities: patterns and

《环境科学与工程前沿(英文)》 2023年 第17卷 第11期 doi: 10.1007/s11783-023-1739-4

摘要:

● We tracked Chinese cities’ MSW disposal infrastructure development history.

关键词: China     Municipal solid waste (MSW)     Landfill     Incineration     Proliferation patterns     Driving forces    

Will biomass be used for bioenergy or transportation biofuels?What drivers will influence biomass allocation

Jinguang HU, William James CADHAM, Susan van DYK, Jack N. SADDLER

《农业科学与工程前沿(英文)》 2017年 第4卷 第4期   页码 473-481 doi: 10.15302/J-FASE-2017168

摘要: Potential competition for biomass for current and future bioenergy/biofuel uses in Brazil, Denmark, Sweden and the USA were compared. In each of these countries, bioenergy and biofuels are already important in their energy mix. However, there is limited competition for biomass between bioenergy (heat/power/residential/industrial) and transportation biofuel applications. This situation is likely to continue until advanced biofuel technology becomes much more commercially established. In each of these countries, biomass is predominantly used to produce bioenergy, even in those regions where biofuels are significant component of their transportation sector (Brazil, Sweden and USA). The vast majority of biofuel production continues to be based on sugar, starch and oil rich feedstocks, while bioenergyis produced almost exclusively from forest biomass with agricultural biomass having a small, but increasing, secondary role. Current and proposed commercial scale biomass-to-ethanol facilities almost exclusively use agriculture derived residues (corn stover/wheat straw/sugarcane bagasse). Competition for biomass feedstocks for bioenergy/biofuel applications, is most likely to occur for agricultural biomass with coproduct lignin and other residues used to concomitantly produce heat and electricity on site at biofuel production facilities.

关键词: bioenergy     biofuel     biomass     renewable energy policy    

Proposed EU legislation to force changes in sewage sludge disposal: A case study

Vojtěch Turek, Bohuslav Kilkovský, Zdeněk Jegla, Petr Stehlík

《化学科学与工程前沿(英文)》 2018年 第12卷 第4期   页码 660-669 doi: 10.1007/s11705-018-1773-0

摘要:

The consequences of changes planned in the European Union legislation relevant to the disposal of sewage sludges are discussed. A specific municipal waste water treatment plant is analyzed in terms of drying and subsequent combustion or pyrolysis of the produced stabilized sludge, and the respective net energy balances are carried out. A simplified economic analysis of the two disposal options is presented, which suggest that combustion of the sludge would be economically infeasible while pyrolysis of the sludge in a modular, self-sufficient container unit can bring a small financial benefit due to the selling of the produced phosphorus-rich biochar.

关键词: sewage sludge     drying     combustion     pyrolysis    

A combination process of mineral carbonation with SO2 disposal for simulated flue gas by magnesia-added

Yingying Zhao, Mengfan Wu, Zhiyong Ji, Yuanyuan Wang, Jiale Li, Jianlu Liu, Junsheng Yuan

《化学科学与工程前沿(英文)》 2019年 第13卷 第4期   页码 832-844 doi: 10.1007/s11705-019-1871-7

摘要: The desulfurization by seawater and mineral carbonation have been paid more and more attention. In this study, the feasibility of magnesia and seawater for the integrated disposal of SO and CO in the simulated flue gas was investigated. The process was conducted by adding MgO in seawater to reinforce the absorption of SO and facilitate the mineralization of CO by calcium ions. The influences of various factors, including digestion time of magnesia, reaction temperature, and salinity were also investigated. The results show that the reaction temperature can effectively improve the carbonation reaction. After combing SO removal process with mineral carbonation, Ca removal rate has a certain degree of decrease. The best carbonation condition is to use 1.5 times artificial seawater (the concentrations of reagents are 1.5 times of seawater) at 80°C and without digestion of magnesia. The desulfurization rate is close to 100% under any condition investigated, indicating that the seawater has a sufficient desulfurization capacity with adding magnesia. This work has demonstrated that a combination of the absorption of SO with the absorption and mineralization of CO is feasible.

关键词: mineral carbonation     wet SO2 disposal     seawater     desulfurization    

NUMERICAL MODELING OF BIOMASS GASIFICATION USING COW DUNG AS FEEDSTOCK

《农业科学与工程前沿(英文)》 2023年 第10卷 第3期   页码 458-467 doi: 10.15302/J-FASE-2023500

摘要:

● Gasification of cow dung was evaluated using Aspen Plus software.

关键词: Aspen Plus     biomass gasification     manure of livestock and poultry     simulation     syngas    

红石岩堰塞湖排险处置与统合管理

刘宁

《中国工程科学》 2014年 第16卷 第10期   页码 39-46

摘要:

本文介绍了云南昭通鲁甸红石岩堰塞湖的基本情况,叙述了排险处置方案编制及组织实施的过程及其考虑,分析了处置效果,从统筹目标、整合力量及系统性等方面阐明了统合管理方法在应对自然灾害等突发公共安全事件中的重要意义和作用,对进一步提高统合管理能力进行了探讨。

关键词: 昭通鲁甸地震     堰塞湖排险     统合管理    

Catalytic conversion of biomass-derived compounds to various amino acids: status and perspectives

《化学科学与工程前沿(英文)》 2023年 第17卷 第7期   页码 817-829 doi: 10.1007/s11705-022-2254-z

摘要: Amino acids are important nitrogen-containing chemicals that have a variety of applications. Currently, fermentation is the widely employed method to produce amino acids; however, the products are mostly limited to natural amino acids in the L-configuration. Catalytic synthesis is an alternative approach for the synthesis of amino acids with different types and configurations, where the use of renewable biomass-based feedstocks is highly attractive. To date, several lignocellulose and triacylglycerol-derived intermediates, typically α-keto acids and α-hydroxyl acids, have been transformed into amino acids via the amination reaction in the presence of additional nitrogen sources (i.e., NH3·H2O). Making full use of inherent nitrogen in biomass (i.e., chitin and protein) to produce amino acids avoids the use of extra nitrogen sources and meets the requirements of green chemistry, which is attracting increasing attention. In this review, we summarize different chemical-catalytic systems for the transformation of biomass to amino acids. An outlook on the challenges and opportunities for more effective production of amino acids from biomass by catalytic methods is provided.

关键词: biomass     amino acids     chitin     nitrogen-containing compounds     lignocellulose    

Review of the direct thermochemical conversion of lignocellulosic biomass for liquid fuels

Jianchun JIANG,Junming XU,Zhanqian SONG

《农业科学与工程前沿(英文)》 2015年 第2卷 第1期   页码 13-27 doi: 10.15302/J-FASE-2015050

摘要: Increased demand for liquid transportation fuels, environmental concerns and depletion of petroleum resources requires the development of efficient conversion technologies for production of second-generation biofuels from non-food resources. Thermochemical approaches hold great potential for conversion of lignocellulosic biomass into liquid fuels. Direct thermochemical processes convert biomass into liquid fuels in one step using heat and catalysts and have many advantages over indirect and biological processes, such as greater feedstock flexibility, integrated conversion of whole biomass, and lower operation costs. Several direct thermochemical processes are employed in the production of liquid biofuels depending on the nature of the feedstock properties: such as fast pyrolysis/liquefaction of lignocellulosic biomass for bio-oil, including upgrading methods, such as catalytic cracking and hydrogenation. Owing to the substantial amount of liquid fuels consumed by vehicular transport, converting biomass into drop-in liquid fuels may reduce the dependence of the fuel market on petroleum-based fuel products. In this review, we also summarize recent progress in technologies for large-scale equipment for direct thermochemical conversion. We focus on the technical aspects critical to commercialization of the technologies for production of liquid fuels from biomass, including feedstock type, cracking catalysts, catalytic cracking mechanisms, catalytic reactors, and biofuel properties. We also discuss future prospects for direct thermochemical conversion in biorefineries for the production of high grade biofuels.

关键词: lignocellulosic biomass     thermochemical     liquid fuels     upgrading     biofuels    

Latest advances in ionic liquids promoted synthesis and application of advanced biomass materials

《化学科学与工程前沿(英文)》 2023年 第17卷 第7期   页码 798-816 doi: 10.1007/s11705-023-2316-x

摘要: The utilization of sustainable resources provides a path to relieving the problem of dependence on fossil resources. In this context, biomass materials have become a feasible substitute for petroleum-based materials. The development of biomass materials is booming and advanced biomass materials with various functional properties are used in many fields including medicine, electrochemistry, and environmental science. In recent years, ionic liquids have been widely used in biomass pretreatments and processing owing to their “green” characteristics and adjustable physicochemical properties. Thus, the effects of ionic liquids in biomass materials generation require further study. This review summarizes the multiple roles of ionic liquids in promoting the synthesis and application of advanced biomass materials as solvents, structural components, and modifiers. Finally, a prospective approach is proposed for producing additional higher-quality possibilities between ionic liquids and advanced biomass materials.

关键词: biomass materials     functional materials     ionic liquids     synthesis     structure-property relationship    

Construction of sustainable, colored and multifunctional protein silk fabric using biomass riboflavin

《化学科学与工程前沿(英文)》 2023年 第17卷 第8期   页码 1131-1139 doi: 10.1007/s11705-023-2321-0

摘要: Riboflavin sodium phosphate has been confirmed as a promising biomass product derived from natural plants. In this paper, a novel method of dyeing and multifunctional modification of silk fabric by impregnation with riboflavin sodium phosphate was proposed, such that protein silk fabric can be endowed with bright yellow color and multi-functionality. The results of this paper confirmed that the pH and concentration of riboflavin sodium phosphate solution are critical factors for dyeing and multifunctional modification. Attractively, the photochromic performance was one of the most distinctive features of the modified silk fabric, and the dyed silk fabric turned into fluorescent green from original yellow under 365 nm ultraviolet lamp. Furthermore, the modified silk fabric exhibited good antibacterial properties with a high inhibition rate of 92% for Escherichia coli. Besides, the flame retardancy of silk fabric was significantly improved after modification. The damaged length of modified silk fabric with 40% owf riboflavin sodium phosphate was lower than 10.4 cm and passed the B1 classification. As revealed by the result of this paper, riboflavin sodium phosphate is sufficiently effective in serving as an eco-friendly multifunctional agent for strengthening the add-value of silk textiles.

关键词: biomass     riboflavin sodium phosphate     silk protein     multifunctional modification     flame retardant    

高放废物地质处置:进展与挑战

王驹

《中国工程科学》 2008年 第10卷 第3期   页码 58-65

摘要:

随着我国核能事业的飞速发展,高水平放射性废物的处理和处置,即将成为一个重大的安全和环保问题。在介绍国内外进展的基础上,重点讨论了高放废物地质处置面临的挑战:处置库场址地质演化的精确预测、深部地质环境特征、多场耦合条件下(中(高)温、应力作用、水力作用、化学作用、生物作用和辐射作用等)深部岩体、地下水和工程材料的行为、低浓度超铀放射性核素的地球化学行为与随地下水迁移行为及处置系统的安全评价。

关键词: 高放废物     地质处置     地下实验室     科学挑战    

Possible solutions for sludge dewatering in China

Wei WANG, Yuxiang LUO, Wei QIAO,

《环境科学与工程前沿(英文)》 2010年 第4卷 第1期   页码 102-107 doi: 10.1007/s11783-010-0001-z

摘要: In China, over 1.43×10 tons of dewatered sewage sludge, with 80% water content, were generated from wastewater treatment plants in 2007. About 60% of the COD removed during the wastewater treatment process becomes concentrated as sludge. Traditional disposal methods used by municipal solid waste treatment facilities, such as landfills, composting, or incineration, are unsuitable for sludge disposal because of its high water content. Disposal of sludge has therefore become a major focus of current environmental protection policies. The present status of sludge treatment and disposal methodology is introduced in this paper. Decreasing the energy consumption of sludge dewatering from 80% to 50% has been a key issue for safe and economic sludge disposal. In an analysis of sludge water distribution, thermal drying and hydrothermal conditioning processes are compared. Although thermal drying could result in an almost dry sludge, the energy consumption needed for this process is extremely high. In comparison, hydrothermal technology could achieve dewatered sewage sludge with a 50%–60% water content, which is suitable for composting, incineration, or landfill. The energy consumption of hydrothermal technology is lower than that required for thermal drying.

关键词: sewage sludge disposal     water content     thermal drying     hydrothermal conditioning    

Emulsification for castor biomass oil

Dongxiang ZHANG, Yuanping LIN, Anmei LI, V. V. TARASOV

《化学科学与工程前沿(英文)》 2011年 第5卷 第1期   页码 96-101 doi: 10.1007/s11705-010-0553-2

摘要: The effect of the emulsifier formula on the stability of castor oil-water system was studied through compounding three groups of emulsifiers from the aspects of stability factor of absorbance, centrifuge stability, demulsification time in quiescence, appearance of the droplets, and viscosity. The best emulsifier formula for castor biomass oil was the composite formula of sorbitan monooleate and polyoxyethylene sorbitan monostearate. Correlation exists between the stability of emulsion and the viscosity/particle size of the droplets, with better stability in the case of greater viscosity or narrower distribution of particle size in the emulsion of castor oil-water system. Methanol added to the castor oil-water system may decrease the viscosity of the emulsion. Comparing the castor oil-water emulsion with methanol-castor oil-water emulsion, the optimal hydrophilic and lipophilic balance (HLB) value based on castor oil-water system was acquired between 6.6 and 7.5, while the optimal HLB value based on the methanol-castor oil-water system was between 5.5 and 6.0. The optimal HLB value of methanol-castor oil-water system gradually moved to that of castor oil-water emulsion with adding more water.

关键词: castor oil     biomass oil     emulsification     stability     viscosity     corrosivity    

标题 作者 时间 类型 操作

mechanism of arsenic capture by a calcium-based sorbent during the combustion of arsenic-contaminated biomass

Mei Lei, Ziping Dong, Ying Jiang, Philip Longhurst, Xiaoming Wan, Guangdong Zhou

期刊论文

Nitrogen-retaining property of compost in an aerobic thermophilic composting reactor for the sanitary disposal

Fan BAI, Xiaochang WANG,

期刊论文

Exploring the development of municipal solid waste disposal facilities in Chinese cities: patterns and

期刊论文

Will biomass be used for bioenergy or transportation biofuels?What drivers will influence biomass allocation

Jinguang HU, William James CADHAM, Susan van DYK, Jack N. SADDLER

期刊论文

Proposed EU legislation to force changes in sewage sludge disposal: A case study

Vojtěch Turek, Bohuslav Kilkovský, Zdeněk Jegla, Petr Stehlík

期刊论文

A combination process of mineral carbonation with SO2 disposal for simulated flue gas by magnesia-added

Yingying Zhao, Mengfan Wu, Zhiyong Ji, Yuanyuan Wang, Jiale Li, Jianlu Liu, Junsheng Yuan

期刊论文

NUMERICAL MODELING OF BIOMASS GASIFICATION USING COW DUNG AS FEEDSTOCK

期刊论文

红石岩堰塞湖排险处置与统合管理

刘宁

期刊论文

Catalytic conversion of biomass-derived compounds to various amino acids: status and perspectives

期刊论文

Review of the direct thermochemical conversion of lignocellulosic biomass for liquid fuels

Jianchun JIANG,Junming XU,Zhanqian SONG

期刊论文

Latest advances in ionic liquids promoted synthesis and application of advanced biomass materials

期刊论文

Construction of sustainable, colored and multifunctional protein silk fabric using biomass riboflavin

期刊论文

高放废物地质处置:进展与挑战

王驹

期刊论文

Possible solutions for sludge dewatering in China

Wei WANG, Yuxiang LUO, Wei QIAO,

期刊论文

Emulsification for castor biomass oil

Dongxiang ZHANG, Yuanping LIN, Anmei LI, V. V. TARASOV

期刊论文